Computer simulation of the process of manufacturing flat ingots of thermoelectric materials based on Bі2Tе3 by vertical zone melting method
Keywords:
simulation, vertical zone melting, thermoelectric material, bismuth tellurideAbstract
The results of the development of a computer model for optimizing the process of manufacturing flat ingots of thermoelectric materials based on Ві2Те3 using the vertical zone melting method are presented. The created model allows one to study the dependence of the crystallization front shape on various technological parameters – the geometric dimensions of the heater and coolers, their temperatures, speed of movement, etc. This makes it possible to carry out multifactorial optimization of technological modes and equipment design, significantly reducing the material costs and time required for conducting similar experimental studies. Bibl. 19, Figs. 3.
References
1. Cao T., Shi X.L., Li M., Hu B., Chen W., Liu W.Di, W. Lyu, MacLeod J., Chen Z.G. (2023). Advances in bismuth-telluride-based thermoelectric devices: progress and challenges. EScience, 3 (3), Article 100122. https://doi.org/0.1016/j.esci.2023.100122.
2. Goldsmid H.J. (2014). Bismuth telluride and its alloys as materials for thermoelectric generation. Materials, 7, 2577-2592. https://doi.org/10.3390/ma7042577.
3. Kuo Chia-Hung, Hwang Chii-Shyang, Jeng Ming-Shan, Su Wei-Sheng, Chou Ya-Wen, Ku Jie-Ren (2010). Thermoelectric transport properties of bismuth telluride bulk materials fabricated by ball milling and spark plasma sintering. Journal of Alloys and Compounds, 496(1–2), 687-690. https://doi.org/10.1016/j.jallcom.2010.02.171.
4. Anatychuk L.I., Hwang Jenn-Dong, Lysko V.V., Prybyla A.V. (2013). Thermoelectric heat recuperators for cement kilns. J.Thermoelectricity, 5,36–42.
5. Anatychuk L.I., Lysko V.V., Kravtsov S.O. (2019). Design of thermoelectric generator for transport high-power starting preheater. J. Thermoelectricity, 5,17–36.
6. Anatychuk L.I., Lysko V.V. (2021). Computer design of a thermoelectric generator for heat and electricity supply to heavy-duty vehicles. J. Thermoelectricity, 2,79–88.
7. Tritt T. (2000). Recent trends in thermoelectric materials research, Part Two (Semiconductors and semimetals, Vol. 70). Academic Press, 2000. 320 p. ISBN-13: 978-0127521794.
8. Zhai R.S., Zhu T.J. (2022). Improved thermoelectric properties of zone-melted p-type bismuth-telluride-based alloys for power generation. Rare Met. 41, 1490–1495. https://doi.org/10.1007/s12598-021-01901-2.
9. Saberi Y., Sajjadi S.A. (2022). A comprehensive review on the effects of doping process on the thermoelectric properties of Bi2Te3 based alloys. Journal of Alloys and Compounds,904, Article 163918. https://doi.org/10.1016/j.jallcom.2022.163918.
10. Saleemi M., Toprak M.S., Li S., Johnsson M., Muhammed M. (2012). Synthesis, processing, and thermoelectric properties of bulk nanostructured bismuth telluride (Bi2Te3). J. Mater. Chem. 2, 725-730. https://doi.org/10.1039/C1JM13880D.
11. Lysko V.V., Tudoroi P.F. (2019). Computer simulation of extrusion process of Bi2Te3 based tape thermoelectric materials. J.Thermoelectricity, 2, 58–65.
12. Anatychuk L.I., Lysko V.V. (2020). Thermoelectricity: Vol. 5. Metrology of thermoelectric materials. Chernivtsi: Bukrek ISBN 978-617-7770-40-3.
13. Anatychuk L.I., Lysko V.V. (2014). On improvement of the accuracy and speed in the process of measuring characteristics of thermoelectric materials. Journal of Electronic Materials, 43(10), 3863–3869. https://doi.org/10.1007/s11664-014-3300-5.
14. Anatychuk L.I., Havrylyuk N.V., Lysko V.V. (2012). Methods and equipment for quality control of thermoelectric materials. Journal of Electronic Materials, 41(6), 1680-1685. https://doi.org/10.1007/s11664-012-1973-1.
15. Nitsovich O.V. (2018). Research on the conditions of forming a flat crystallization front when growing Ві2Те3 based thermoelectric material by vertical zone melting method. J.Thermoelectricity. 3,76-82.
16. Anatychuk L.I., Nitsovich O.V. (2018). Simulation of the effect of thermal unit velocity on the process of growing Ві2Те3 based materials by vertical zone melting method. J.Thermoelectricity, 3, 76-82.
17. Nitsovich O.V. (2018). Computer simulation of Ві2Те3 crystallization process in the presence of electrical current. J.Thermoelectricity, 5,12-21.
18. COMSOL Multiphysics, v. 6.0. www.comsol.com. COMSOL AB, Stockholm, Sweden. 2021.
19. Reddy J.N. (2006). An introduction to the finite element method (Third ed.). McGraw-Hill. ISBN 9780071267618.