Simulation of the effect of thermal unit velocity on the process of growing Ві2Tе3 based materials by vertical zone melting method

Authors

  • L.I. Anatychuk 1. Institute of Thermoelectricity of the NAS and MES of Ukraine, 1 Nauky str., Chernivtsi, 58029, Ukraine. 2. Yuriy Fedkovych Chernivtsi National University 2 Kotsiubynskyi str., Chernivtsi, 58012, Ukraine
  • O.V. Nitsovich 1. Institute of Thermoelectricity of the NAS and MES of Ukraine, 1 Nauky str., Chernivtsi, 58029, Ukraine. 2. Yuriy Fedkovych Chernivtsi National University 2 Kotsiubynskyi str., Chernivtsi, 58012, Ukraine

Keywords:

simulation, vertical zone melting, thermoelectric material, bismuth telluride

Abstract

The paper presents the results of computer simulation of the process of growing Ві2Те3 based thermoelectric materials by vertical zone melting method. It was found that, depending on the velocity of the heater and coolers, not only the curvature of the crystallization front changes, but also its shape. At temperatures of the heater and coolers Th = 1058K, Th = 303K for velocities greater than 1.25 cm/h, the crystallization front along the entire crystal becomes convex into the solid phase, but at lower velocities it changes its shape from convex to concave along the grown sample. Bibl. 5, Fig. 6.

References

Goltsman B.M., Kudinov V.A., Smirnov I.A. (1972). Poluprovodnikovyie termoelektricheskiie materialy na osnove Bi2Te3 [Semiconductor thermoelectric materials based on Bi2Te3]. Moscow: Nauka [in Russian].

U.G. Pfan. (1970). Zonnaya plavka [Zone melting]. V.N.Vigdorovich (Ed.) [in Russian]

Nitsovich O.V. (2018). Research on the conditions of forming a flat crystallization front when growing Ві2Те3 based thermoelectric material by vertical zone melting method. J.Thermoelectri-

city, 3, 76-82.

Nitsovich O.V. (2018). Computer simulation of Ві2Те3 crystallization process in the presence of electrical current. J.Thermoelectricity, 5, 12-21.

COMSOL Multiphysics Modeling Software. COMSOL INC. – Retrieved from: https://www.comsol.com/.

How to Cite

Anatychuk, L., & Nitsovich, O. (2024). Simulation of the effect of thermal unit velocity on the process of growing Ві2Tе3 based materials by vertical zone melting method. Journal of Thermoelectricity, (4), 54–62. Retrieved from http://jte.ite.cv.ua/index.php/jt/article/view/74

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